This page last modified (mo/day/year) :
1. ARTICLES IN REFEREED JOURNALS
2. REVIEWS
3. CHAPTERS IN BOOKS OR SERIALS
4. Ph.D. THESIS
ARTICLES IN REFEREED JOURNALS
| 106. |
D.A. Rankic, M. Parvez, B.A. Keay*, 2012, “3,3’-Substituted BINAP Derivatives Containing C-Bound Substituents: Applications in Asymmetric Hydrogenations Reactions.”, Tetrahedron Asymmetry, 23, 754-763. |
| 105. |
D. Lucciola, B.A. Keay*, 2011, "Further Developments of an Enantioselective Palladium-Catalyzed Polyene Cyclization: Surprising Solvent and Ligand Effects.", Synlett, 1618-1622. |
| 104. |
D.A. Rankic, D. Lucciola, B.A. Keay*, 2010, "Application of 3,3'-Disubstituted xylBINAP Derivatives in Inter- and Intramolecular Asymmetric Heck/Mizoroki Reactions", Tetrahedron Lett., 51, 5724-4727. PDF |
| 103. |
T.K. Wood, W.E. Piers*, B.A. Keay, M. Parvez, 2010, “Synthesis and Comparative Characterization of 9-Boraanthracene, 5-Boratetracene and 6-Borapentacene Stabilized by the H2IMes Carbene ”, Chem. Eur J., 16, 211. PDF |
| 102. |
J.R. Henderson, J.P. Chesterman, M. Parvez, B. A. Keay*, 2010, “Diastereoselective Diels-Alder Reactions with a Novel Allenyl-containing Spiro-amido Chiral Auxiliary”, Journal of Organic Chemistry, 75, 988-991. PDF |
| 101. |
D.A. Rankic, J.M. Hopkins, M. Parvez, B.A. Keay*, 2009, “3,3’-Disubstituted xylBINAP Derivatives: Synthesis, Resolution and Applications”, Synlett, 2513-2517.PDF |
| 100. |
J.R. Henderson, M. Parvez, B.A. Keay*, 2009, “A Concise Diels-Alder Strategy for the Synthesis of (+)-Dihydrodrimenin, (+)-Albicanol, and (+)-Albicanol Acetate”, Organic Letters, 11, 3178-3181. PDF |
| 99. |
T.K. Wood, W.E. Piers*, B.A. Keay, M. Parvez, 2009, “Cyclic Boronium Ions: Precursors to Persistent Neutral Radicals”, Chem. Commun., 5147-5149. PDF |
| 98. |
T.K. Wood, W.E. Piers*, B.A. Keay, M. Parvez, 2009, “N-Heterocyclic Carbene Stabilized 9-Boraanthracene Derivatives”, Angew. Chem. Int. Ed. 48, 4009-4012. PDF |
| 97. |
W.L. Benoit, M. Parvez, B.A. Keay*, 2009, " Development of P-stereogenic 2-phenyl-1,3,2-oxazaphosphorine ligands and the impact of stereoelectronic effects on their unexpected sensitivity to oxidation."Tetrahedron Asymmetry, 20, 69-77. PDF |
96. |
K.M. Muller, B.A. Keay*, 2008, “Regioselective Synthesis of the CD Rings of Viridin”, Synlett, 1236-1238. PDF |
| 95. |
E.
Gorobets, M. Parvez, B.A. Keay*, 2008, “Unprecedented Intramoleuclar
Nucleophilic Nucleophilic Aromatic Additions of Allyloxy Anions to
Diphenylphosphinoyl Substituted Benzene Rings”, Synlett, 129-133. PDF |
| 94. |
J.R.
Henderson, M. Parvez, B.A. Keay*, 2007, “Diastereoselective Diels-Alder
Reactions of a Novel Cyclopropenyl-Containing Chiral Auxiliary”, Organic Letters, 9, 5167-5170. DOI: 10.1021/ol702280q |
| 93. |
B.M.M.
Wheatley, B.A. Keay*, 2007, “Use of Deuterium Labeling Studies to
Determine the Stereochemical Outcome of Pd Migrations during an
Asymmetric Intermolecular Heck Reaction”, Journal of Organic Chemistry, 72, 7253-7259. DOI: 10.1021/jo071119u |
| 92. |
J.M.
Hopkins, E. Gorobets, B.M.M. Wheatley, M. Parvez, B.A. Keay*, 2006,
“Applications of 3,3'-Disubstituted BINAP Derivatives in Heck
Reactions”, Synlett, 3120-3124.PDF |
| 91. |
T.K. Wood, W.E. Piers*, B.A. Keay, M. Parvez, 2006, “1-Borabarrelene Derivatives via Diels-Alder Additions to Borabenzenes”, Organic Letters, 8, 2875-2878. DOI: 10.1021/ol061201w |
| 90. |
E.
Gorobets, R. McDonald, B.A. Keay*, 2006, “A Novel Chiral Auxiliary for
Intramolecular Ullmann Couplings for the Preparation of MeO-BIPHEP and
its 3,3'-Disubstituted Derivatives”, Organic Letters, 8, 1483-1485.DOI: 10.1021/ol060484p |
| 89. |
E.
Gorobets, M. Parvez, B.M.M. Wheatley, B.A. Keay*, 2006, “Use of 1H NMR Chemical Shifts to Determine the Absolute Configuration and Enantiomeric Purity for
Enantiomers of 3,3'-Disubstituted-MeO-BIPHEP Derivatives”, Canadian Journal of Chemistry, 84, 93-98.PDF |
| 88. |
J.M.
Hopkins, S.A. Dalrymple, M. Parvez, B.A. Keay*, 2005, “3,3'-Disubstituted BINAP
Derivatives: Synthesis, Resolution and Applications in Asymmetric
Hydrogenations”, Organic Letters, 7, 3765-3768. DOI: 10.1021/ol051413d |
| 87. |
E.
Gorobets, B.M.M. Wheatley, J.M. Hopkins, R. McDonald, B.A. Keay*, 2005,
“Avoiding the Classical Resolution During the synthesis of MeO-BIPHEP
and 3,3'-Disubstituted Derivatives”, Tetrahedron Letters, 46, 3843-3846. doi:10.1016/j.tetlet.2005.03.183 |
| 86. |
D.
Balcells, F. Maseras, B.A. Keay, T. Ziegler*, 2004, “Polyene
Cyclization by a Double Intramolecular Heck Reaction. A DFT Study”, Organometallics, 23, 2784-2796. DOI: 10.1021/om034310c |
| 85. |
E.
Gorobets, G.-R. Sun, B.M.M. Wheatley, M. Parvez, B.A. Keay*, 2004,
“Synthesis, Resolution and Applications of 3,3’-Di-RO-MeO-BIPHEP
Derivatives”, Tetrahedron Letters, 45, 3597-3601. doi:10.1016/j.tetlet.2004.03.073 |
| 84. |
P.F.
Mugford, S.M. Lait, B.A. Keay, R.J. Kazlauskas*, 2004,
“Enantiocomplementary Enzymatic Resolution of the Chiral Auxiliary
cis,cis-6-(2,2-Dimethylpropanamido)spiro-[4.4]nonan-1-ol and the
Moleuclar Basis for the High Enantioselectivity of Subtilisin
Carlsberg”, ChemBioChem: A European Journal of Chemical Biology, 5, 980-987. PDF |
| 83. |
N.G.Anderson, M. Parvez, B. McDonald, B.A. Keay*, 2004, “Synthesis, Resolution and Applications of BINAPFu”, Canadian Journal of Chemistry, 82, 145-161.PDF |
| 82. |
S.M.
Lait, M. Parvez, B.A. Keay*, 2004, “Synthesis of a Novel
Spiro-Phosphino-Oxazine Ligand and its Application to Pd-Catatyzed
Asymmetric Allylic Alkylation”, Tetrahedron Asymmetry, 15, 155-158. doi:10.1016/j.tetasy.2003.10.031 |
| 81. |
T.D. Vickers, B.A. Keay*, 2003, “Synthesis of (+/-)-Curcumene Ether”, Synlett, 1349-1351. |
| 80. |
S.M.
Lait, M. Parvez, B.A. Keay*, 2003, “Synthesis of a
1,3-Spiro-Amino-Alcohol Derived Chiral Auxiliary and its Application to
the Diels-Alder Reactions”, Tetrahedron Asymmetry, 14, 749-756. doi:10.1016/S0957-4166(03)00051-X |
| 79. |
N.G.
Andersen, P.D. Ramsden, D. Che, M. Parvez, B.A. Keay*, 2001, “A Simple
Resolution Procedure Using the Staudinger Reaction for the Preparation
of P-Stereogenic Phosphine Oxides”, Journal of Organic Chemistry, 66, 7478-7486. DOI: 10.1021/jo015909u |
| 78. |
M. Parvez, I.R. Hunt, B.A. Keay, 2001, "2-(1-Naphthyl)cyclohexyl 2-methylfuran-3-carboxylate", Acta Crystallographica, E57, 804-805.PDF |
| 77. |
M. Parvez, I.R. Hunt, B.A. Keay, 2001, "2-Phenylcyclohexyl 3-furancarboxylate", Acta Crystallographica, E57, 802-803.PDF |
| 76. |
M. Parvez, I.R. Hunt, B.A. Keay, 2001, "2-(1-Naphthyl)cyclohexyl 3-furancarboxylate", Acta Crystallographica, E57, 800-801.PDF |
| 75. |
R. Alibés, F. Busquè, P. de March*, M. Figueredo, J. Font, M.E. Gambino, B.A. Keay, 2001, “Acetals of Gama–oxo Alpha,Beta-Unsaturated Esters in Nitrone Cycloadditions. Regio- and Stereochemical Implications”, Tetrahedron Asymmetry, 12, 1747-1756. doi:10.1016/S0957-4166(01)00294-4 |
| 74. |
S.Y.W.
Lau, B.A. Keay*, 2001, "A Highly Efficient Strategy for the Synthesis
of 3-Substituted Salicylic Acids By Either Directed Ortho-Lithiation or
Halogen-metal Exchange of Substituted MOM Protected Phenols Followed by
Carboxylation", Canadian Journal of Chemistry 79, 1541-1545.PDF |
| 73. |
N.G.
Andersen, B. McDonald, B.A. Keay*, 2001, "Synthesis, Resolution and
Application of (+/-)-2,2'-Bis(di-2-furylphosphino)-1,1'-Binaphthalene", Tetrahedron Asymmetry 12, 263-269. doi:10.1016/S0957-4166(01)00035-0 |
| 72. |
S.Y.W.
Lau, N.G. Andersen, B.A. Keay*, 2001, "Optimization of
Palladium-Catalyzed Polyene Cyclizations: Suppression of Competing
Hydride Transfer from Tertiary Amines with Dabco and an Unexpected
Hydride Transfer from 1,4-Dioxane.", Organic Letters, 3, 181-184. DOI: 10.1021/ol006740u |
| 71. |
N.G.
Andersen, M. Parvez, B.A. Keay*, 2000, "Synthesis, Resolution and
Applications of
(+/-)-2,2'-Bis(diphenylphosphino)-3,3'-binaphtho[b]furan", Organic Letters, 2, 2817-2820. DOI: 10.1021/ol006238+ |
| 70. |
M.J. Burke, M.M. Allan, M. Parvez, B.A. Keay*, 2000, "Synthesis and Applications of 1R,5S,6S-6-(2,2-Dimethylpropanamido)spiro[4.4]nonan-1-ol As a Chiral Auxiliary in Diels-Alder Reactions", Tetrahedron: Asymmetry, 11, 2733-2739. doi:10.1016/S0957-4166(00)00242-1 |
| 69. |
D. Che, N.G. Andersen, S.Y.W. Lau, M. Parvez, B.A. Keay*, 2000, "Synthesis and Applications of (R)- and (S)-7,7'-Dimethoxy-2,2'-Bis(diphenylphosphino)-1,1'-Binaphthalene", Tetrahedron: Asymmetry, 11, 1919-1925. doi:10.1016/S0957-4166(00)00148-8 |
| 68. |
N.G.
Andersen, P.D. Ramsden, D. Che, M. Parvez, B.A. Keay*, 1999, "A New
Resolution Procedure for the Preparation of P-Chiral Phosphine Oxides", Organic Letters, 1, 2009-2011. DOI: 10.1021/ol991174s |
| 67. |
M.M.
Allan, P.D. Ramsden, M.J. Burke, M. Parvez, B.A. Keay*, 1999,
"Reassignment of the Absolute Configuration of the Baker's Yeast
Reduction of (+/-)-Ethyl 1-Allyl-2-Oxocyclopentanecarboxylate", Tetrahedron: Asymmetry, 10, 3099-3101. doi:10.1016/S0957-4166(99)00334-1 |
| 66. |
J.A. Nieman, B.A. Keay*, 1999, "An Efficient Synthesis and Resolution of (+/-)- Spiro[4.4]nonane-1,6-diol.", Syn. Commun., 29, 3829-3840. PDF |
| 65. |
S.Y.W.
Lau, B.A. Keay*, 1999, "Remote Substituent Effects on the Enantiomeric
Excess of Intramolecular Palladium-Catalyzed Polyene Cyclizations", Synlett, 605-607. |
| 64. |
E.
Bures, P.G. Spinazze, G. Beese, I.R. Hunt, C. Rogers, B.A. Keay*, 1997
"Regioselective Preparation of 2,4-, 3,4-, and 2,3,4- Substituted Furan
Rings. Part 1: [1,4] Oxygen to Carbon and [1,4] Carbon to Oxygen Silyl
Migrations of Silyl Ethers and Esters Attached to Furan and Thiophene
Rings", Journal of Organic Chemistry, 62, 8750-8759. DOI: 10.1021/jo971098b |
| 63. |
E.
Bures, J.A. Nieman, S. Yu, P.G. Spinazze, J.-L.J. Bontront, I.R. Hunt,
A. Rauk, B.A. Keay*, 1997 "Regioselective Preparation of 2,4-, 3,4-,
and 2,3,4- Substituted Furan Rings. Part 2: The Regiospecific
Lithiation of 2-Silylated-3-Substituted Furan Rings", Journal of Organic Chemistry, 62, 8741-8749. DOI: 10.1021/jo971097j |
| 62. |
B.A.
Keay*, S.P. Maddaford, W.A. Cristofoli, N.G. Andersen, M.S. Passafaro,
N.S. Wilson, J.A. Nieman, 1997, "Synthetic Adventures Along a Rocky
Mountain Road", Canadian Journal of Chemistry, 75,
1163-1171. (This paper is based on the Merck Frosst Centre for
Therapeutic Research Award Lecture given at the 79th CIC Conference
held in St. John's :NFLD in June 1997.)PDF |
| 61. |
S. Woo, M. Parvez, B.A. Keay*, 1997 "Regio- and Stereo-selective Ring Openings of Unsymmetrical Oxatricyclo Adducts", Canadian Journal of Chemistry, 75, 665-680.PDF |
| 60. |
N.S. Wilson, B.A. Keay*, 1997, "Mild Base Mediated Desilylation of Phenolic Silyl Ethers", Tetrahedron Letters, 38, 187-190. doi:10.1016/S0040-4039(96)02270-8 |
| 59. |
N.G. Andersen, S.P. Maddaford, B.A. Keay*, 1996, "A Modified in Situ Suzuki Cross-Coupling of Haloarenes for the Preparation of C2 Symmetric Biaryls", Journal of Organic Chemistry 61, 9556-9559. DOI: 10.1021/jo9617880 |
| 58. |
B.E. Carpenter, I.R. Hunt, B.A. Keay*, 1996, "A Short Efficient Preparation of (+)- and (-)-trans-2-Phenylcyclohexanol", Tetrahedron: Asymmetry, 7, 3107-3108. doi:10.1016/0957-4166(96)00409-0 |
| 57. |
J.A. Nieman, B.A. Keay, 1996, "cis,cis-Spiro[4.4]nonane-1,6-diol: A New Chiral Auxiliary for the Asymmetric Diels-Alder Reaction". Tetrahedron: Asymmetry, 7, 3521-3526. doi:10.1016/S0957-4166(96)00459-4 |
| 56. |
S.P.
Maddaford, N.G. Andersen, W.A. Cristofoli, B.A. Keay*, 1996, "Total
Asymmetric Synthesis of (+)-Xestoquinone by an Asymmetric Palladium
Catalyzed Polyene Cyclization", Journal of the American Chemical Society, 118, 10766-10773. DOI: 10.1021/ja960807k |
| 55. |
N.S. Wilson, B.A. Keay*, 1996, "A One Step Desilylation-Oxidation of Aliphatic t-Butyldimethylsilyl Ethers", Journal of Organic Chemistry, 61, 2918-2919. DOI: 10.1021/jo952210d |
| 54. |
N.G.
Andersen, S.P. Maddaford, B.A. Keay*, 1996, "The Synthesis of
Functionalized Naphthalenes From Substituted
1-Methoxybenzocyclobutenes", Journal of Organic Chemistry, 61, 2885-2887. DOI: 10.1021/jo951978v |
| 53. |
S. Woo, B.A. Keay*, 1996, 'The Synthesis of the C15-C23 Segment of Venturicidin A", Synlett, 135-137. |
| 52. |
I.R.
Hunt, A. Rauk, B.A. Keay*, 1996, "Why Do Catalytic Quantities of Lewis
Acid Generally Yield More Product than 1.1 Equivalents in the
Intramolecular Diels-Alder Reaction with a Furan Diene? Part 2. AM1
Calculations and Mathematical Simulation of the Equilibria", Journal of Organic Chemistry, 61, 751-757. DOI: 10.1021/jo951220b |
| 51. |
M.S. Passafaro, B.A. Keay*, 1996, "A One Pot in situ Combined Shapiro-Suzuki Reaction", Tetrahedron Letters, 37, 429-433. doi:10.1016/0040-4039(95)02210-4 |
| 50. |
N.S. Wilson, B.A. Keay*, 1996, "A Mild Palladium(II) Catalyzed Desilylation of Phenolic tert-Butyldimethylsilyl Ethers", Tetrahedron Letters, 37, 153-156. doi:10.1016/0040-4039(95)02120-5 |
| 49. |
J.A. Nieman, B.A. Keay*, 1995, "An Improved Synthesis and Resolution of (+/-)-cis,cis-2,2'-Spirobiindan-1,6-diol", Tetrahedron: Asymmetry, 6, 1575-1583. doi:10.1016/0957-4166(95)00201-Y |
| 48. |
J.A.
Nieman, B.A. Keay*, M. Kubicki, D. Yang, A. Rauk, D. Tsankov, H.
Wieser, 1995, "Determining Absolute Configuration by Spectroscopic
Means: The Vibrational Circular Dichroism Spectrum of (+)-1S,5S,6S- and (-)-1R,5R,6R-Spiro[4.4]nonane-1,6-diol", Journal of Organic Chemistry, 60, 1918-1919.PDF |
| 47. |
I.R.
Hunt, C. Rogers, S. Woo, A. Rauk, B.A. Keay*, 1995, "Why Do Catalytic
Quantities of Lewis Acid Generally Yield More Product than 1.1
Equivalents in the Intramolecular Diels-Alder Reaction with a Furan
Diene? Competitive Complexation NMR Studies Provide an Answer", Journal of the American Chemical Society, 117, 1049-1056. PDF |
| 46. |
S.P Maddaford, B.A. Keay*, 1994, "Scope and Limitations of the Palladium Catalyzed Cross-Coupling Reactions of in situ Generated Organoboranes with Aryl and Vinyl Halides", Journal of Organic Chemistry, 59, 6501-6503.PDF |
| 45. |
A.
Rauk*, I.R. Hunt, B.A. Keay, 1994, "Lewis Acidity and Basicity: An Ab
Initio Study of Proton and BF3 Affinities of Oxygen-Containing Organic
Compounds", Journal of Organic Chemistry, 59, 6808-6816.PDF |
| 44. |
W.
Cristofoli, B.A. Keay*, 1994, "Palladium Catalyzed Polyene
Cyclizations: An Approach to the Pentacyclic Carbon Framework of
Halenaquinone and Xestoquinone", Synlett, 625-627. |
| 43. |
S.
Woo, B.A. Keay*, 1994, "Thermodynamically Controlled Asymmetric
Induction: Application with the Intramolecular Diels-Alder Reaction
with a Furan Diene", Tetrahedron Asymmetry 5, 1411-1414. doi:10.1016/0957-4166(94)80098-7 |
| 42. |
J.A. Nieman, B.A. Keay*, 1994, "A Facile Preparation of 2,4-Disubstituted Furans", Tetrahedron Lett., 35, 5335-5338. doi:10.1016/S0040-4039(00)73493-9 |
| 41. |
J.A. Nieman, M. Parvez, B.A. Keay*, 1993, "An Improved Synthesis and Resolution of (+/-)-Spiro[4.4]nonane-1,6-diol", Tetrahedron: Asymmetry, 4, 1973-1976. doi:10.1016/S0957-4166(00)82242-9 |
| 40. |
C.
Rogers, B.A. Keay*, 1993, "Diastereoselective Intramolecular
Diels-Alder Reactions of the Furan Diene: The Synthesis of
1,4-Epoxycadinane", Canadian Journal of Chemistry, 71, 611-623. PDF |
| 39. |
M.
Parvez, S. Yu, B.A. Keay*, 1993, "The X-ray Crystal Structure of the
p-Bromobenzoate Derivative of
3-(t-Butyldimethylsilyl)-5-hydroxy-2(5H)furanone", Acta Crystallographica, C, 49, 992-993.PDF |
| 38. |
C. Rogers, B.A. Keay*, 1992, "The Effect of Lewis Acids on the Intramolecular Diels-Alder Reaction of the Furan Diene", Canadian Journal of Chemistry, 70, 2929-2947.PDF |
| 37. |
S.
Yu, G. Beese, B.A.Keay*, 1992, "An Improved Synthesis of
2-Substituted-3-Furoic Acids Leading to an Intramolecular Diels-Alder
Reaction Between a Dienophile and Furan Diene Both Containing An
Electron Withdrawing Group", J. Chem. Soc., Perkin Trans. I, 2729-2731.PDF |
| 36. |
S.
Woo, B.A. Keay*, 1992, "Regio- and Stereo-selective SN2' Openings of
Substituted 11-Oxatricyclo[6.2.1.01,6]undec-9-en-5-ones", Tetrahedron Letters, 33, 2661-2664. doi:10.1016/S0040-4039(00)79051-4 |
| 35. |
C.
Rogers, B.A. Keay*, 1991, "Catalytic Methylaluminum Dichloride: An
Efficient Method for Accelerating the Intramolecular Diels-Alder
Reaction of the Furan Diene", Tetrahedron Letters, 32, 6477-6480. doi:10.1016/0040-4039(91)80197-E |
| 34. |
W.
Cristofoli, B.A. Keay*, 1991, "A Palladium Catalyzed Cross-Coupling
Between Furyl-borates (Generated in situ) and Organohalides", Tetrahedron Letters, 32, 5881-5884. doi:10.1016/S0040-4039(00)79416-0 |
| 33. |
S. Yu, B.A. Keay*, 1991, "The Regiospecific C-4 Lithiation of 2-(t-Butyldimethylsilyl)-3-Furoic Acid", J. Chem. Soc., Perkin Trans. 1, 2600-2601.PDF |
| 32. |
B.A. Keay*, J.-L.J. Bontront, 1991, "A Facile Preparation of 4-Aryl-3-Substituted Furans", Canadian Journal of Chemistry, 69, 1326-1330.PDF |
| 31. |
E.
Piers*, R.W. Friesen, B.A. Keay, 1991, "Intramolecular Palladium(0)
Catalyzed Coupling of Enol Triflates and Vinylstanne Functions. New
Annulation Sequences Leading to Bicyclic Diene Systems", Tetrahedron, 47, 4555-4570. doi:10.1016/S0040-4020(01)86462-0 |
| 30. |
C. Rogers, B.A. Keay*, 1991, "The Effects of Lewis Acids on the Intramolecular Diels-Alder Reaction of the Furan Diene", Synlett, 353-354. |
| 29. |
G. Beese, B.A. Keay*, 1991, "A Simple Preparation of 2-Silylated-3-Furoic and 2-Silylated-3-Thiophene Carboxylic Acids", Synlett, 33-34. |
| 28. |
B.A.
Keay*, C. Rogers, J.-L.J. Bontront, 1989, "Wagner-Meerwein
Rearrangements of Substituted 11-Oxatricyclo[6.2.1.01,6]undec-9-enes", J. Chem. Soc., Chemical Communications, 1872-1875.PDF |
| 27. |
P.G. Spinazzé, B.A. Keay*, 1989, "The 1,4 Carbon to Oxygen Silyl Migrations of Various Furan and Thiophene Systems", Tetrahedron Letters, 30, 1765-1769. doi:10.1016/S0040-4039(00)99574-1 |
| 26. |
C.
Rogers, B.A. Keay*, 1989, "The Effect of Side Chain Substituents on the
Intramolecular Diels-Alder Reaction of the Furan Diene: The Synthesis
of 1,4-Epoxycadinane", Tetrahedron Letters, 30, 1349-1352. doi:10.1016/S0040-4039(00)99462-0 |
| 25. |
B.A. Keay*, P.W. Dibble, 1989, "High Pressure Intramolecular Diels-Alder Reactions of the Furan Diene", Tetrahedron Letters, 30, 1045-1046. doi:10.1016/S0040-4039(01)80354-3 |
| 24. |
T. Leung, R. Aroca, B.A. Keay, B. Mutus, 1988, “Intramolecular Interactions in 2’-O-Anthraniloyl and 2’-O(N-Methylanthraniloyl) Derivatives of cAMP and cGMP”, Biochemistry, 27, 3102-3102. (Refereed Conference Proceeding) |
| 23. |
E.J.
Bures, B.A. Keay*, 1988, "The Regiospecific Formation and Reactions of
4-Lithio-2-(t-Butyldimethylsilyl)-3-(Hydroxymethyl)Furan", Tetrahedron Letters, 29, 1247-1250. doi:10.1016/S0040-4039(00)80267-1 |
| 22. |
E.J.
Bures, B.A. Keay*, 1987, "The 1,4 Oxygen to Carbon Silyl Migrations of
Various 3-[(Trialkylsilyl)-oxymethyl]Furans and Thiophenes", Tetrahedron Letters, 28, 5965-5968. doi:10.1016/S0040-4039(00)96838-2 |
| 21. |
B.A. Keay*, 1987, "Intramolecular Diels-Alder Reaction of the Diene Unit of Furan in 2.0M CaCl2", J. Chem. Soc., Chemical Communications, 419-421.PDF |
| 20. |
E.
Piers*, J.M. Chong, B.A. Keay, 1985, "Conjugate Addition of
(Trimethylstannyl) Copper Reagents to ,-Acetylenic N,N-Dimethyl Amides.
Trapping of the Intermediates with Electrophiles", Tetrahedron Letters, 26, 6265-6268. doi:10.1016/S0040-4039(01)84573-1 |
| 19. |
E.
Piers*, R.W. Friesen, B.A. Keay, 1985, "Alkylation of Carbonyl
Compounds with -Iodo-2-Trimethylstannylalk-1-enes. Novel Annulation
Sequences Leading to Diene Systems", J. Chem. Soc., Chemical Communications, 809-810.PDF |
| 18. |
B.A.
Keay, R. Rodrigo*, 1985, "The Diels-Alder Reaction of
4-Hydroxy-7-Methoxyisobenzofuran with Methyl Vinyl Ketone: A General
Method for the Identification of Some Regiomeric Naphthols", Canadian Journal of Chemistry, 62, 735-739.PDF |
| 17. |
B.A. Keay, R. Rodrigo*, 1984, "A Convergent Synthesis of ()-Daunomycinone", Tetrahedron, 40, 4597-4602. doi:10.1016/S0040-4020(01)91520-0 |
| 16. |
N.J.
Taylor, B.A. Keay, R. Rodrigo*, 1984, "The Crystal Structures of
2-endo-Acetyl and
2-endo-Caromethoxy-1,4-Epoxy-6,7-Dimethoxy-1,2,3,4-Tetrahydronaphthalenes", Canadian Journal of Chemistry, 62, 1099-1102. PDF |
| 15. |
B.A.
Keay, D. Rajapaksa, R. Rodrigo*, 1984, "Anomalous 5-endo-trig
Reversals: General Reactions of 7-Oxabicyclo[2.2.1]Heptenes and
Heptanes", Canadian Journal of Chemistry, 62, 1093-1098. PDF |
| 14. |
Rajapaksa,
B.A. Keay, R. Rodrigo*, 1984, "Shikimic Acids from Furan: Methods of
Stereocontrolled Access to 3,4,5-Trioxygenated Cyclohexenes", Canadian Journal of Chemistry, 62, 826-827. PDF |
| 13. |
B.A. Keay, H.P. Plaumann, R. Rodrigo*, 1983, "Hydroxyacetals, Phthalans and Isobenzofurans Therefrom", Canadian Journal of Chemistry", 61, 1987-1995. PDF |
| 12. |
B.A. Keay, R. Rodrigo*, 1983, "An Exceptional 5-endo-trig Reversal: A Convergent Synthesis of Daunomycinone", Canadian Journal of Chemistry", 61, 637-639. PDF |
| 11. |
B.A.
Keay, R. Rodrigo*, 1982, "An Intramolecular Diels-Alder Reaction of
Isobenzofuran: A Convergent Synthesis of Resistomycin", Journal of the American Chemical Society, 104, 4725-4727. PDF |
| 10. |
B.A.
Keay, D. Lee, R. Rodrigo*, 1980, "A New Method for the Generation of
Isobenzofurans: A Simple Entry to Substituted Naphthalenes", Tetrahedron Letters, 21, 3663-3666. doi:10.1016/S0040-4039(00)78738-7 |
| 9. |
H.P. Plaumann, B.A. Keay, R. Rodrigo*, 1979, "The Lithiation of Aromatic Acetals", Tetrahedron Letters, 20, 4921-4924. doi:10.1016/S0040-4039(01)86750-2 |
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REVIEWS
| 8. |
S.M. Lait, D.A. Rankic, B.A. Keay*, 2007, “1,3-Amino-Alcohols and Their Derivatives in Asymmetric Organic Synthesis”, Chemical Reviews, 107, 767-796. DOI: 10.1021/cr050065q |
| 7. |
N.G. Andersen, B.A. Keay, 2001, "2-Furyl Phosphines as Ligands for Transition Metal- Mediated Organic Synthesis", Chem. Rev. , 101, 997-1030. DOI: 10.1021/cr000024o |
| 6. |
B.A. Keay, 1999, "The Synthesis of Multi-substituted Furan Rings: The Role of Silicon", J. Chem. Soc., Chem. Rev. , 28, 209-215.PDF |
| 5. |
S. Woo, B.A. Keay*, 1996, "SN2' and "SN2' Like" Ring Openings of Oxa-n-Cyclo Systems", Synthesis, 669-686. |
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CHAPTERS IN BOOKS OR SERIALS
| 4. |
J.M. Hopkins, B.A. Keay*, P.W. Dibble, 2008, "Furans and their Benzo Derivatives: Applications", Chapter 3.08 in Comprehensive Heterocyclic Chemistry II, Elsevier, 571-624. |
| 3. |
B.A. Keay, 2001, "Arylsilanes" in Science of Synthesis, Volume Editor: I. Fleming, George Thieme Verlag, Volume 4, Section 33, 685-712. |
| 2. |
B.A.
Keay*, I.R Hunt, 1999, "Aspects of the Intramolecular Diels-Alder
Reaction of a Furan Diene (IMDAF) Leading to the Formation of
1,4-Epoxydecalin Systems" in Advances in Cycloaddition, Editor: M. Harmata, JAI Press Inc., Stamford Connecticut, Vol. 6, 173-210. |
| 1. |
B.A. Keay*, P.W. Dibble, 1996, "Furans and their Benzo Derivatives: Applications", Chapter 2.08 in Comprehensive Heterocyclic Chemistry II, Pergamon Press, 395-436. |
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Ph.D. THESIS
B.A.
Keay, 1983, "Diels-Alder Reactions of Furan and Isobenzofurans.
Properties of the Oxabicyclo Adducts and Their Application to the
Synthesis of Daunomycinone and Resistomycin", University of Waterloo,
Waterloo, Ontario, Canada.
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