Orbital interaction
theory is a conceptual construct that lies at the very heart of modern
organic chemistry. Comprising a comprehensive set of principles for
explaining chemical reactivity, orbital interaction theory originates in
a rigorous theory of electronic structure that also provides the basis
for the powerful computational models and techniques with which chemists
seek to describe and exploit the structures and thermodynamic stabilities
of molecules.
Orbital Interaction Theory of Organic Chemistry, Second Edition introduces students to the fascinating world of organic chemistry at the mechanistic level with a thoroughly self-contained, well-integrated exposition of orbital interaction theory and its applications to modern organic chemistry. Professor Rauk reviews concepts of symmetry and orbital theory, and explains reactivity in common functional groups and reactive intermediates in terms of orbital interaction theory. Aided by numerous examples and worked problems, he guides readers through basic chemistry concepts, such as acid and base strength, nucleophilicity, electrophilicity, and thermal stability (in terms of orbital interactions), and provides various computational models for describing those interactions.
Updated and expanded, this latest edition of Orbital Interaction Theory of Organic Chemistry includes a completely new chapter on organometallics, increased coverage of density functional theory, many new application examples, and worked problems. The text is complemented by an interactive somputer program, SHMO, which displays orbitals graphically and is available at the following Web site: www.chem.ucalgary.ca/SHMO/.
Orbital Interaction Theory of Organic Chemistry, Second Edition is an excellent text for advanced level undergraduate and graduate students in organic chemistry. It is also a valuable working resource for professional chemists seeking guidance on interpreting the quantitative data produced by modern computational chemists.